Construction materials

ABSTRACT

A sulfur oxide gas is passed through a fluidized bed of porous calcium oxide particles to form a lamination or coating of calcium sulfate over the external surfaces of the calcium oxide particles. There results a core of substantially pure calcium oxide and an outer lamination of calcium sulfate. The particles are then quenched rapidly from a temperature of approximately 850*F. to ambient temperature and a plurality of cracks result in the lamination of calcium sulfate. The resulting product is then used for making plaster or can be blended with other products to make cementitious products and the like.

United States Patent [191 Lin [ Jan. 21, 1975 CONSTRUCTION MATERIALS [76] Inventor: Ping-Wha Lin, Angola, Ind.

[22] Filed: Apr. 10, 1972 [21] Appl. No.: 242,699

Related US. Application Data [63] Continuation-impart of Ser. No. 36,861, May 13,

I970, abandoned.

[52] US. Cl. 106/109, 106/118 [51] Int. Cl C04b 11/00 [58] Field of Search 106/63, 103, 105, 109,

106/118, DIG. 1; 423/244, 36, 861

[56] References Cited UNITED STATES PATENTS 3,343,908 9/1967 Wickert 423/244 3,411,865 11/1968 Pijpers et al. 423/244 FOREIGN PATENTS OR APPLICATIONS 21,667 2/1968 Japan 106/103 Primary ExaminerJ. Poer Attorney, Agent, or Firm-John A. Young [57] ABSTRACT A sulfur oxide gas is passed through a fluidized bed of porous calcium oxide particles to form a lamination or coating of calcium sulfate over the external surfaces of the calcium oxide particles. There results a core of substantially pure calcium oxide and an outer lamination of calcium sulfate. The particles are then quenched rapidly from a temperature of approximately 850F. to ambient temperature and a plurality of cracks result in the lamination of calcium sulfate. The resulting product is then used for making plaster or can be blended with other products to make cementitious products and the like.

11 Claims, 5 Drawing Figures PATEHTED I975 861 .930

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i l I fir SULFUR r EL ROsTATIc i 2 I -%Y-I I TOR :22 I 24 o'w I I LUE GAS l 25 I -ROTARY FEEDER 28 MECHANICAL) I4 Ie EgaSI CATALYTIC REA ikiJ-d OXIDATTISN 650 OR ABOVE :95 E '(PRg ERRED VE d. as ORABO Z6 o. 88%R) EE-U E L.

3 I-ROTARY sOLID INC 42 PRODUCT I eHfiwlfER 44 STORAGE BIN so Ia MATERIALs FOR PLAs ER BLENDER BLENDED MATERIALS FOR CONSTRUCTION OR STORAGE A w CONSTRUCTION MATERIALS RELATED APPLICATION This application is a continuation-in-part of copending U.S. application Ser. No. 36,861, filed May 13, 1970, now abandoned. Said application was refiled as continuation application Ser. No. 235,343, filed Mar. 16, 1972, now U.S. Pat. No. 3,781,408.

BACKGROUND OF THE INVENTION The invention relates to air pollution control, and more particularly to pollution control of effluent gasses that contain fly ash and sulfur-bearing gasses.

Air pollution is a very serious and urgent international problem. The sources of air pollution are the products of combustion and are almost always numerous and widespread. Alone, the United States is currently pouring pollutants into the atmosphere at the staggering rate of 160 million tons a year. Our air has become so poisonous that it is actually altering global weather patterns.

Much of the air pollutants are in the form of fly ash and sulfur-bearing gasses discharged by coalburning electrical power generating plants or other industries, or even by oil-consuming heaters in private homes or other buildings. These pollutants actually cause untold millions or billions of dollars of annual damage by corroding buildings and structures, and also cause innumerable cases of human suffering from various respiratory diseases plus the above-mentioned global effects. Yet, under any foreseeable circumstances, we will have to burn more and more fuel to meet the demand of rapidly growing population requiring for each person evermore heating comfort and electrical power. And the fuel we shall use will not contain much less, but likely contain more sulfur and fly ash.

This invention discloses methods and equipment designed not only to remove these pollutants but to convert them into useful and salable by-products, such as construction materials.

While not limited thereto, the invention is herein described as applied to combustion gasses discharged into the air from a power plant and containing fly ash and sulfur-bearing gasses.

An important object of the invention is to control the pollution of air from effluent gasses containing sulfur oxide gas and solid particles such as fly ash;

Another object is to remove fly ash and sulfur oxide bearing gasses from combustion gasses in an economical manner;

Yet another object of this invention is to collect air pollutants and convert them into useful by-product forms;

A further object is to use the collected pollutants for special treatment and economical manufacture of cinder block or other construction materials;

Another object is to provide means and methods for controlling the composition of the combustion gasses through automatic process control of the pollutantstreating processes, based on monitored data relating to the type and amount of pollutants in the combustion gasses, and the efficiency of the various treating processes, with due regard to the fuel quality and requirement of the manufactured construction materials;

A further object is to produce from the air pollutants useful construction materials of novel characteristics.

An overall object of the invention is to provide a continuous process for effectively removing sulfur dioxide as a pollutant from combustion gasses and to do so by means of substantially converting the sulfur dioxide and then exposing such sulfur trioxide to a fluidized bed of calcium oxide under such reaction conditions that virtually all of the sulfur trioxide is reacted to form calcium sulfate and is hence removed from the outflow of combustion product gasses.

Further objects and advantages of my invention will appear as the specification proceeds.

SUMMARY OF THE INVENTION My invention discloses methods and equipments for removing S0 S0 and fly ash in combustion gasses discharged as air pollutants from fossil fuel-burning, heating furnaces, The removal is accomplished by means of dust collectors and catalytic oxidation of S0 to followed by controlled reaction of 50 with excess lime to form CaSO The unspent lime, CaSO, and collected fly ash are used together with cement for the manufacture of construction materials, the percentage of CaSO being carefully regulated to control the setting time of the cement. Preferably, the proportion of the excess lime is automatically regulated by process control devices designed with due regard to fuel quality and requirement of the construction materials and operating according to the monitored sulfur-level of the combustion gasses.

BRIEF DESCRIPTION OF THE DRAWINGS The preferred form of my invention is illustrated in the accompanying drawings, in which:

FIG. 1 is a photomicrograph of 700X magnification of a calcium oxide particle coated with calcium sulfate and produced as a by-product of the present invention and illustrating the unique cracked configuration in the outer layer of calcium sulfate;

FIG. 2 is a photomicrograph of the same particle as FIG. 1 but at 3,000X magnification and showing even more clearly details of the core, coating and cracks in the coating;

FIG. 3 shows a flow diagram of the pollution control process and monitoring equipments used therefor; and

FIGS. 4 and 5 are diagrammatic cross-sectional views of unspent lime particles having CaSO, surface coatmgs.

DESCRIPTION OF THE PREFERRED EMBODIMENTS In the flow diagram of FIG. 3 is shown a furnace 10 in which fossil fuel containing sulfur and inert residues is burned with air, which is preheated for better heating efficiency. The combustion gasses from the furnace 10 contain S0 S0 and suspended solid particles consisting of noncumbustible residue and partially burned fuel.

According to .l. W. Mellor (in A Comprehensive Treatise on Inorganic and Theoretical Chemistry, Vol. X, Wiley, N. Y. 1961, pp. to 91), sulfur burns in air to form mostly S0 but with a few percent by weight of S0 in the oxidation products. When the oxidation products are drawn over ferric oxide, such as is usually present in coal, the quantity of 80 can be increased to 17 percent. If the air contains moisture, a little sulfuric acid (H 80 is also formed. These two compounds are desirable to the practice of my invention, as will be shown.

The combustion gasses are passed through an air heater 12 and are regulated to an elevated temperature, preferably to about 900F. before being passed through a mechanical dust collector l4 and an electrostatic precipitator 16 system for the separation of solid particles in the form of fly ash. The dust collector system comprises a mechanical dust collector 14 to remove large fly ash particles and a high temperature electrostatic precipitator 16 to separate the finer particles in the combustion gasses. Mechanical dust collectors usually separate entrained particles in gasses by centrifugal force. Electrostatic precipitators may be used for the removal of practically any material suspended in gasses by electrically attracting these particles.

The dust collector system should have nearly 100% efficiency in solid-particle removal, particularly with regard to those particles which may poison catalysts in the catalytic oxidation convertor to be described. Separated fly ash particles are collected and sent to a blender or storage bin 18.

The flue gas, i.e., combustion gasses cleaned of the suspended particles, then passes through a sulfur-level monitor 20, which determines the level of sulfur concentration in the flue gas, and has a computerized controller 21 and a servo connection 22 to a lime supply 24 connected by supply line 25 to lime reactor 28. The flue gas contains sulfur oxides SO mainly as S and S0 and is then passed through a catalytic oxidation convertor 26. A typical catalytic convertor contains vanadium catalyst having a very large surface to volume ratio and operated at elevated temperatures 650F.950F., preferably between 850F. to 880F., to oxidize S0 into S0 according to the following reaction:

2 (g) VA 02 (g) 3 (g) It is evident that increasing the pressure of the convertor, which is preferable in some cases, shifts the chemical equilibrium toward the right thereby enhancing the efficiency of the desired conversion of S0 to S0 However, according to R. F. Bovier (in Proceedings ofrhe American Power Conference, Vol. 26, 1964), even at one atmospheric pressure, the conversion efficiency is typically over 90 percent.

The flue gas coming into the lime reactor 28 generally contains around 9 percent of moisture. The following reactions take place at above 650F. in the reactor:

H SO (g) CaO (g) CaSO, (s) H O (g) CaO and CaSO. can absorb a large quantity of water at room temperature. At high temperatures, however, these compounds absorb very little or no water. Hence, these compounds coming out of the lime reactor 28 can be moisture-free, and can even remain so if immediately packaged in dry atmosphere.

The 50;, may also combine with CaO directly to form C3504 CaO (s) S0 (g) CaSO (s) For reasons of increased agitation, better heat transfer, high reaction efficiency, small floor space, economy installation and operation and other factors, the lime reactor 28 or reacting system should be continuously operated and comprises one or more countercurrent, multi-stage, fluidized CaO reactors.

Since the S0 concentration in the stack gas is quite low, the monitor 20 is responsive to the SO content which is essentially S0 While the feed rate of lime is not high, its feed rate is correlated to the S0 content by means of the computerized controller 21 which, by means of servo line 22 regulates the correct feed rate of lime from line supply 24 through a rotary feeder in line 25 to lime reactor 28. Under usual reaction conditions approximately 35 mg of pulverized lime is sufficient for each liter of flue gas for substantially total sulfur oxide gas removal. The feed rate however, may be varied by a factor of about five, depending partly upon the sulfur concentration in the flue gas, partly on the desired degree of conversion from CaO to CaSO, in the solid product.

The feed rate of flue gas as well as the sulfur oxide gas content is variable but at all times the lime supply is correlated thereto. The controller is programmed with due regard to the fuel quality and requirements of the manufactured construction materials and by the servo operation to effect a near total removal of the S0 content of the flue gasses. A monitor 29 is located in the flue gas outlet line 30 from the line reactor 28 so that if for any reason the equipment is not performing satisfactorily the operation will signal a malfunctioning to indicate the need for adjustment repair or shut down.

The exit stream from the lime reactor 28 consists of particles of different degrees of conversion from CaO to CaSO The average conversion of this stream depends mainly on two factors:

A. The rate of reaction of lime particles in the reactor environment, and

B. The residence time distribution of the solids in the lime reactor.

The chemical reaction between S0 and CaO is highly exothermic. But since the concentration of 50;; in the flue gas is low (i.e., 2,000 ppm. by volume), the heat generated from the lime reaction can be made to just meet the heating requirement for the cold, freshly added lime. Therefore, it is expected that the reactor 28 will be operated at the same temperature as the incoming flue gas, i.e., above 650F. and preferably above 850F. The cold lime may be efficiently heated by spirallying down inside the lime reactor to extract some heat from the hot gasses discharged from the reactor.

In case the lime particles are large, the cold lime particles may be injected into lime reactor and are subjected to sudden heating from ambient temperature to above 850F. CaO and CaSO, are brittle materials which can be easily failed by tension, but seldom by compression. During sudden heating, the center of lime particle is under maximum tension. The value of maximum tension is dependent on the size of particle. The larger the size of particle, the higher value the maximum tension at center. Interior cracks can form and, if sufficiently severe, can break the lime particle to pieces. Fragmentation of large lime particle is desirable in S0 removal, for it increases surface area/volume ratio, resulting in an effective chemical reaction and finer solid product.

The particle size of CaO is important in the fluidization process, as it affects solids flow characteristics, bed densities, losses of solids, and equipment erosion. According to Othmer (See e.g., Fluidization. Reinhold Publishing Corporation, N. Y., 1956), a broad range of particle sizes gives better fluidization than a narrow range; and fine, pulverized materials are better than coarse. Commercially available, ground quicklime, typically about 100 percent passing No. 8 sieve and 2 to 4 percent passing No. 100 sieve, can be used in the fluidized lime reactor, Pulverized lime 100 percent passing No 20 sieve, also 85 percent 95 percent passing lOO sieve is available and is satisfactory. The governing factors, in the fluidized lime reactor design are: densities of solids, particle sizes, concentration of S in the stack gas, and flow rate of stack gas. Knowing all these factors, skilled chemical engineers can design or select the reactor to meet individual requirements.

The CaO size distribution is particularly important in the practice of my invention for another reason. CaO is fed purposely in excess of the amount required for complete conversion of S0, to CaSO Hence, some CaO particles are barely, or even not at all, changed at the surface or interior. Other extremely fine CaO particles 32 (FIGS. 1, 2, 4, 5), may however, be completely converted to CaSO But most CaO particles are only partially converted on their surfaces, giving cracked 13 coatings 15 of CaSO, 34 on cores of unspent CaO 35 as shown in FIG. 4. CaO may be porous, like a sponge (FIG. 5). In this case, the surface of the pores 37 are also converted into CaSO, (FIG. 5). These new structures of unspent lime achieve novel results that will be discussed.

The surface layers of CaSO are only of the order of 15 microns (IO cm) in thickness. This is because the residence time t, of the lime particles in the lime reactor is estimated to be in the range of 10 to 100 minutes, depending on the particle size distribution, gas flow rate, fluidized reactor design, and other variables. The diffusion coefficient of S0 through CaSO layers, D, to reach and react with the inner, unspent CaO can be considered to be about lO cm /sec. at a temperature above 880F. The preferred temperature is about 850F. The penetration depth, or surface CaSO, layer thickness, is then about Dt,, or in the range of 7.8 to 23.2 microns. These CaSO, layers contain cracks 13 because of the sudden cooling in quenching chamber 46 from the preferred temperature above 850F. to or below ambient temperature.

The reacted lime particles are discharged from lime reactor 28 through line 42 having a rotary feeder 44 aiid into a quenching chamber 46. When the hot CaSO coated lime particles are cooled from a preferred temperature above 850F. in quenching chamber to or below ambient temperature the sudden thermal shock gives rise to the beforedescribed cracks 13 which have an important functional aspect. The cracks in the CaSO, coating cover, do not suppress the water reaction of the CaO particles used as a construction material and is entirely and definably new. Such a unique, cracked structure has never been used in actual practice, nor even suggested by any prior practices. The core 46 is substantially pure CaO and the particle size of cracked, calcium sulfate coated particles is as hereinbefore defined. Hence, the covered, unspent CaO still reacts readily with the fly ash to be discussed later.

The solid product from fluidized lime reactor 28 will contain well-blended, unspent lime and CaSO, and is collected in storage bin 50. Each particle of the solid product has only CaO in the core and pure CaSO, cracked coating, since the CaSO, coatings are formed on CaO particles in the reactor which has a very narrow temperature range, i.e., 850F. to 880F. The reacting gasses in the reactor contain over percent S0 if the convertor is operated in optimum temperature of 850F. to 880F. Hence the reaction is well controlled, and the reaction product is simple and pure. The product contains CaO and CaSO, and each compound coacts with the other and serves its unique and useful function as construction materials. It is understood that the feed rate may affect the percentage of unspent lime in the outflow of solids. The properties of the solid can be modified by altering the unspent lime percentage. The solid product can be used:

A. For making flooring plaster It is known that large pure CaSO, particles set very very slowly, usually in a number of days or weeks. In fact, hard-burned CaSO, can never set by itself (J. W. Mellor, A Comprehensive Treatise of Inorganic and Theoretical Chemistry, Vol. 3, pp. 774-775. Longmans). When the solid product is mixed with water, the lime in the core areas will leach out and serve as an accelerator in CaSO, hardening. The initial set takes place in less than 24 hours. In making flooring plaster by hydration, the CaSO, to CaO ratio by weight should generally be about 1:3, though in cases this same ratio by weight may be reduced to 1:4 or increased to 14:1 in the extreme. If when the solid product is further calcined to 1,000C. for 1 hour, the unspent lime and CaSO, become sintered and form a very hard flooring plaster upon hydration.

B. For reclaiming fly ash The solid materials collected from the dust collector 14 and precipitator 16 system and those from the lime reactor 42 are then blended together in blender 18. The blending ratio may change the unspent lime concentration and the percentage of S0 in the mixture. The properties of the mixture can be modified by altering the blending ratio in order to make the mixture particularly suitable for a specific application. The blended mixture of CaSO unspent lime, and fly ash may be sold as such, for uses such as in construction materials, soil conditioners, liquid waste treatments, and the like. However, in many cases, cement clinker, clay, rocks (in the form of sand, gravel, or chips and fragments) may be added to the blended mixture for the manufacture of brick, cinder blocks or other concrete structure members. In concrete manufacture, the gypsum serves the purpose of regulating the setting time of cement. If CaSO, concentration is too high, there is the danger of gypsum expansion during hardening because of a quick reaction of CaSO, with tricalcium aluminate (in the fly ash) to form a low-density, large-volume compound called calcium sulphoaluminate. Hence, the maximum allowable gypsum concentration has generally been specified at about 5 percent by weight of cement. lf anhydrous sulfate is used, it sets with very little expansion.

Fly ash with its silica and alumina readily reacts with lime in the presence of water to form a compound of cementitious value (Pozzolanic activity). The insoluble cement compounds which might normally at ordinary temperature, take seven days or more to develop, can be secured in steam curing either autoclave or nonautoclave, in a matter of a few hours. Meanwhile, the unspent lime acts itself through the cracks as an accelerator in the solid product for the setting of the anhydrous CaSO enhancing an early strength of the concrete. With a proper mixing design, a high strength concrete can be produced by the interaction of cement clinker, fly ash, anhydrous CaSO and lime in the solid product. If the lime particles are covered on their surfaces with thin (l-micron) cracked CaSO layers, such reactions will quickly expose the normally unreachable inside of CaSO layers for their actions in the blended mixture. Thus, the CaSO, is greatly and rapidly activated in its entirety, permitting minimum concentration of CaSO to be used in the mixture for given results in cement setting control; or resulting in complete, effective usage of CaSO in the final products.

In ordinary concrete mixtures, the CaSO, (gypsum) is in the form of large particles, up to several millimeters in diameter. The regulating effect of these CaSO, particles is slow and incomplete, being governed by solid-state diffusion. Further, the gypsum expansion in these particulate CaSO, introduces high tensile stress concentration and causes cracks. Hence, the range of CaSO, concentration is often very narrow and critical, i.e., from 4 to 5 percent by weight, of cement produced. On the other hand, the CaSO, from my invention has the new, film (about microns thick) structure covering the unspent lime particles. The surfaceto-volume ratio in this CaSO is very high, being increased over the conventional particulate CaSO, by a factor estimated to exceed 10. The CaSO reaction is now fast and complete, thereby allowing much reduced CaSO concentration in the mixture. At the same time, even much higher CaSO concentration is tolerable because the high stress build-up is not present.

The expansion of anhydrous calcium sulfate is small as compared with gypsum and since the calcium sulfate is uniformly distributed throughout the product there I5 I10 OCCUTI'CI'ICC OI less occurrence Of SIICSS concentration. In view of the thinness of and presence of cracks in the CaSO surface layer, the range of CaSO, in my new concrete mixture can be widened (safely to 2-8 percent by weight of CaSO fly ash mixture) and is non-critical.

C. For making cement A carefully blended mixture of the solid product, clay, shale, and pyrites is charged to a kiln which is fired with pulverized coal and the end product is cement and exit gasses containing high percent of S0 When the solid product, the particles with lime in core area surrounded by cracked CaSO is heated to above 2,000F. but below 2,550F. in a rotating furnace, S0 and 50:, are released, leaving CaO behind:

CaSO Ca0 S0 (in oxidizing atmosphere) 2CaSO 2CaO 280 0 Additions such as iron pyrites, iron oxide and lead oxide increase the speed of decomposition and lower the temperature of decomposition. The exit gas from the furnace, rich in S0 and 50;, can be used for H 30 or ammonium sulphate production. The regenerated CaO together with the unspent lime from the solid product are recycled to the lime reactor for further SO removal. By recycling the CaO, materials handling problem will be greatly minimized.

Dust particles in the gas discharged from the lime reactor are also separated by an electrostatic precipitator 52 or other means. The effluent gas will now be free of S0 S0 and dust. To conserve energy, the same gas is introduced into an air preheater 54 where the temperature drops to about 250F. before discharging as stack gas effluent. Since the effluent gas still has relatively high temperatures, moisture contained therein will not condense in the stack, and its dispersion in the atmosphere is swift.

I have thus solved a problem of air pollution, and satisfied a long-standing need for a commercially acceptable system for air pollutants disposal. However, the process is not to be construed as limited to the particular forms described herein, since these are to be regarded as illustrative rather than restrictive. For example, engineers can readily use the principle of this invention to design air pollution control equipments for other polluting industries such as oil refining, coal coking, metal smelting, ore roasting, and waste incinerating. Furthermore, chemicals other than CaO may be used to stabilize at least one of the S0 and S0 gasses to form stable, non-gaseous chemical reaction product which can be easily disposed. For example, magnesia, MgO, closely resembles CaO, is almost invariably present in commercial lime. It reacts with S0 to form MgSO just like CaO, but it does not combine with silica or alumina to form compounds of cementitious value as construction materials. Since the slaking of magnesia is accompanied by an increase in volume and cracking of the hardened concrete, the allowable magnesia contents in cement is limited to 5 percent. In addition, fixed-bed lime reactors can be substituted and designed to replace the fluidized bed reactor hereinbefore described.

Although the present invention has been illustrated and described in connection with a few selected example embodiments, it will be understood that these are illustrative of the invention and are by no means restrictive thereof. It is reasonably to be expected that those skilled in this art can make numerous revisions and adaptations of the invention and it is intended that such revisions and adaptations will be included within the scope of the following claims as equivalents of the invention.

What I claim is:

l. A process for producing improved materials of construction comprising the steps of forming a fluidized bed of calcium oxide, passing a substantially continuous flow of sulfur trioxide containing gasses through said fluidized bed while maintaining a substantially constant temperature above 650F. and below the disintegration temperature of the CaSO to develop a coating of calcium sulfate on cores of substantially unreacted calcium oxide, continuously withdrawing calcium sulfate coated calcium oxide particles, and rapidly quenching such particles to form a plurality of thermal shock induced cracks throughout the surfaces of the calcium sulfate particles.

2. The process in accordance with claim 1 including the step of continuously monitoring the sulfur trioxide content of the incoming flow and proportioning the calcium oxide which constitutes said fluid bed to the available SO whereby the ratio of unspent calcium oxide to calcium sulfate coating is proportioned in a preferred ratio.

3. The process in accordance with claim 2 wherein the coating of calcium sulfate is produced within a thickness range of from about 7.8 to about 23.2 microns.

4. The process in accordance with claim 1 wherein the calcium oxide is formed of spongy lime particles which are loosely cohered together and wherein the calcium sulfate coating is developed throughout the interstices of the spongy calcium oxide material.

5. The process in accordance with claim 1 wherein coated calcium oxide is blended with water and thoroughly mixed to form flooring plaster.

6. The process in accordance with claim 1 including packaging calcium oxide particles having a coating of calcium sulfate in an anhydrous atmosphere to form a moisture free solid product.

7. A process for producing improved materials of construction comprising passing sulfur oxide bearing gasses which originate as the oxidation product of burning fossil fuels, through a catalyst to convert substantially all of the sulfur dioxide to sulfur trioxide, then feeding the sulfur trioxide containing gasses into a particulate calcium oxide lime reactor for a time period to effect substantially complete reaction of the sulfur trioxide with the exposed particulate calcium oxide surfaces to form a calcium sulfate coating on said particulate calcium oxide and quenching such coated calcium oxide particulate material to form a plurality of thermal-shock-induced cracks in the surface of the calcium sulfate coatings.

8. The process in accordance with claim 7 wherein the temperature within the lime reactor is not less than about 850F.

9. The process in accordance with claim 8 wherein the inflowing calcium oxide particles are subjected to a sudden heating from ambient temperature to reactor temperature of said lime reactor to effect heat-induced fracture of the lime particles to smaller particles thereof.

10. The process in accordance with claim 7 wherein the lime reactor is maintained at a substantially constant temperature within a range of about 850F. to about 880F.

11. A plastering material formed in accordance with the process of claim 7 wherein the calcium sulfate coating is in a weight ratio to unreacted calcium oxide in parts by weight of from about 1/4 to about l4/l, 

2. The process in accordance with claim 1 including the step of continuously monitoring the sulfur trioxide content of the incoming flow and proportioning the calcium oxide which constitutes said fluid bed to the available SO3 whereby the ratio of unspent calcium oxide to calcium sulfate coating is proportioned in a preferred ratio.
 3. The process in accordance with claim 2 wherein the coating of calcium sulfate is produced within a thickness range of from about 7.8 to about 23.2 microns.
 4. The process in accordance with claim 1 wherein the calcium oxide is formed of spongy lime particles which are loosely cohered together and wherein the calcium sulfate coating is developed throughout the interstices of the spongy calcium oxide material.
 5. The process in accordance with claim 1 wherein coated calcium oxide is blended with water and thoroughly mixed to form flooring plaster.
 6. The process in accordance with claim 1 including packaging calcium oxide particles having a coating of calcium sulfate in an anhydrous atmosphere to form a moisture free solid product.
 7. A process for producing improved materials of construction comprising passing sulfur oxide bearing gasses which originate as the oxidation product of burning fossil fuels, through a catalyst to convert substantially all of the sulfur dioxide to sulfur trioxide, then feeding the sulfur trioxide containing gasses into a particulate calcium oxide lime reactor for a time period to effect substantially complete reaction of the sulfur trioxide with the exposed particulate calcium oxide surfaces to form a calcium sulfate coating on said particulate calcium oxide and quenching such coated calcium oxide particulate material to form a plurality of thermal-shock-induced cracks in the surface of the calcium sulfate coatings.
 8. The process in accordance with claim 7 wherein the temperature within the lime reactor is not less than about 850*F.
 9. The process in accordance with claim 8 wherein the inflowing calcium oxide particles are subjected to a sudden heating from ambient temperature to reactor temperature of said lime reactor to effect heat-induced fracture of the lime particles to smaller particles thereof.
 10. The process in accordance with claim 7 wherein the lime reactor is maintained at a substantially constant temperature within a range of about 850*F. to about 880*F.
 11. A plastering material formed in accordance with the process of claim 7 wherein the calcium sulfate coating is in a weight ratio to unreacted calcium oxide in parts by weight of from about 1/4 to about 14/l. 